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Ikeura, Hiromi*; Sekiguchi, Tetsuhiro
Japanese Journal of Applied Physics, 58(SI), p.SIIC04_1 - SIIC04_4, 2019/08
Times Cited Count:0 Percentile:0(Physics, Applied)The electronic structure of the unoccupied conduction band of polycrystalline chloroaluminum phthalocyanine was investigated by X-ray absorption spectroscopy (XAS) near the Cl K-edge. XAS spectra were recorded in total electron yield (TEY) and partial Auger electron yield (AEY) modes. Partial AEY spectra were measured using normal and spectator Cl KLL Auger yields as a function of photon energy. Although the TEY spectrum showed a broad shape; that was difficult to deconvolute curve fitting, the normal and spectator AEY spectra clearly showed that *(Cl-Al) transition splits into two competitive peaks attributed to the core excitons (localized with a core hole) and conduction band (delocalized without a core hole). The existence of a band-like peak in the Cl K-edge XAS is evidence that the Cl axial ligand participates in forming the conduction band. Thus, band-like electron transport is expected to occur in the oligomer-like (-Al-Cl-Al-) site.
Sekiguchi, Hiromi*; Sekiguchi, Tetsuhiro
Atomic Collision Research in Japan, (23), p.82 - 83, 1997/00
no abstracts in English
Sekiguchi, Tetsuhiro; Sekiguchi, Hiromi*; Tanaka, Kenichiro*
Surface Science, 390(1-3), p.199 - 203, 1997/00
Times Cited Count:4 Percentile:33.02(Chemistry, Physical)no abstracts in English
Sekiguchi, Hiromi*; Sekiguchi, Tetsuhiro; Tanaka, Kenichiro*
Photon Factory Activity Report, (14), P. 18, 1996/00
no abstracts in English