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Journal Articles

Unoccupied conduction band of chloroaluminum phthalocyanine

Ikeura, Hiromi*; Sekiguchi, Tetsuhiro

Japanese Journal of Applied Physics, 58(SI), p.SIIC04_1 - SIIC04_4, 2019/08

 Times Cited Count:0 Percentile:0(Physics, Applied)

The electronic structure of the unoccupied conduction band of polycrystalline chloroaluminum phthalocyanine was investigated by X-ray absorption spectroscopy (XAS) near the Cl K-edge. XAS spectra were recorded in total electron yield (TEY) and partial Auger electron yield (AEY) modes. Partial AEY spectra were measured using normal and spectator Cl KL$$_{2,3}$$L$$_{2,3}$$ Auger yields as a function of photon energy. Although the TEY spectrum showed a broad shape; that was difficult to deconvolute curve fitting, the normal and spectator AEY spectra clearly showed that $$Cl 1srightarrow $$ $$sigma$$*(Cl-Al) transition splits into two competitive peaks attributed to the core excitons (localized with a core hole) and conduction band (delocalized without a core hole). The existence of a band-like peak in the Cl K-edge XAS is evidence that the Cl axial ligand participates in forming the conduction band. Thus, band-like electron transport is expected to occur in the oligomer-like (-Al-Cl-Al-) site.

Journal Articles

Ion desorption induced by site-selective excitation of oxygen 1s electrons

Sekiguchi, Hiromi*; Sekiguchi, Tetsuhiro

Atomic Collision Research in Japan, (23), p.82 - 83, 1997/00

no abstracts in English

Journal Articles

Applications of a photoion-photoion-coincidence technique to the study of photon-stimulated ion-desorption process following K-shell excitation

Sekiguchi, Tetsuhiro; Sekiguchi, Hiromi*; Tanaka, Kenichiro*

Surface Science, 390(1-3), p.199 - 203, 1997/00

 Times Cited Count:4 Percentile:33.02(Chemistry, Physical)

no abstracts in English

Journal Articles

Ion desoprtion following the oxygen 1s electron excitation of adsorbed formate

Sekiguchi, Hiromi*; Sekiguchi, Tetsuhiro; Tanaka, Kenichiro*

Photon Factory Activity Report, (14), P. 18, 1996/00

no abstracts in English

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